Directly writing 3D structures into supporting mediums is a relatively new developing technology. The liquid-like solid (LLS) materials are developed as supporting mediums, that possesses the self-healing ability and tunable yield stress. Because the components of this emulsion glass are mostly water and oil, it exhibits chemical stability when exposed to UV radiation and high temperature. Based on the above features, this emulsion glass can be regarded as a new kind of LLS material for supporting mediums.