Solar-driven triple-electrode PFC is a new clean energy process. It can simultaneously accomplish the photogeneration of electricityphotodegradation of organic pollutants by unlimited solar energy. H2O2 can be generated from water splitting in a green processobtain the high energy density similar to H2. The PFCs that comprise triple-electrode were designedconstructed for H2O2 productionfuel cell, respectively with treatment of organic wastewater. Proceeding in the way, a portable triple-photoelectrode PFC device was assembled to generation electricity with additional functions of providing safer drinking water. The novel fuel cell can also be engineering scaled up to provide electricity for a familycommunity.